Tag Archives: delta

How do i prepare for airborne school?

Me and my cousin are going to join the army and hopefully make it to delta (fingers crossed). The presrequisits, i believe include being certified as airborne. I’ve never liked the feeling of adrenaline ex: rollor coasters really arent my thing. Water slides dont really bother me though.

I read that you have to be able to run a distance in however much time so i started to run 2 miles a day on my tread mill at home.
THE QUESTION:
What else can i do to get in peek physical condition?
How can i overcome my fear of adrenaline?

Free Energy vs. Rate?

I know that spontaneity (negative free energy. negative delta G) do not necessarily mean that the rate is fast. But if the negative delta G value is large, thus, K is large, can you assume the process is fast? Why or why not?

How can I convert a 3 phase 415 Volt delta induction motor to 3 phase 240 Volts delta?

This is a pico hydro power system. The motor output is 4.5 kW.

Free energy and equilibrium constant K?

I am confused about why delta G (DG) = 0 when a system is at equilibrium. I know DG=0 because of the equation DG = -RTlnK and K=1. However, I thought K is a constant that is specific to any reaction, and when something is in equilibrium Q=K, and K doesn’t have to be 1 (in fact, K usually is never 1, but instead, something very small or big, like 6×10^-5 or 7×10^2). So, if a reaction is at equilibrium (a reaction with an eq. constant K that is NOT equal to 1), then DG will not equal to 0. If this is true, then I don’t understand why the textbook tells me DG = 0 when the system is at equilibrium, with K = 1. (I don’t understand why K has to be 1 at equilibrium, since K is a constant that can be any number) Please explain. Thanks.

Tabulated values of chemical thermodynamic properties seem inconsistent. What am I misunderstanding?

The table in the back of my wife’s chemistry textbook tabulates values of the standard enthalpy of formation delta-Hf0, the standard entropy S0, and the standard free energy of formation delta-Gf0, for a wide variety of elements and compounds, all evaluated at 25C. As I understand it, they should be connected by the relationship

delta-Gf0 = delta-Hf0 – T*S0

They aren’t. For instance, for liquid water, it gave

delta-Hf0 = -286 kJ/mole
S0 = 69.96 J/(mole K)
delta-Gf0 = -237.2 kJ/mole

25C corresponds to T = 298.16 K , so by my calculations detla-Gf0 should be

-286 kJ/mole – 298.16 K * (69.96 J/(mole K) / 1000 (kJ/J)) = -307 kJ/mole

None of the entries in the table work out as I expected, which rules out a typo. I’ve checked with other sources, and they all agree tolerably well with the values tabulated in this textbook. What am I misunderstanding?

Chemistry: Equilibrium Questions?

Calculate the equilibrium constant for the following reaction at 80 degrees Celcius. Also, Delta G(final (not)), the standard free energy of formation for Ni(CO)4 (g) = -587.4 kJ/mol. Assume that Delta G (final (not)) is temperature independent.

Ni(s) + 4CO (g) —> <—– Ni(CO)4 (g)

how do you calculate the equilibrium constant if given the standard free energy of formation (delta Gf) at298K

how do you calculate the equilibrium constant if given the standard free energy of formation (delta Gf) at298K